OChem Lingo

Students, and sometimes experts, often forget or confuse themselves with the never-ending terms and abbreviations in organic chemistry. In this page, I have put in, as many as possible, the terms often found in organic chemistry and their description. This includes some characterisation terms that may be encountered in research papers. I’ll add more as I remember/find more!

Each set of terms is ordered alphabetically so you can easily find them. And here’s the index.

A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z

At the end of each lists, you’ll find the “Back to top” link, so you can go back and forth between the lists and the index.

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A

Term or Abbreviation Also Known As Description
ACN acetonitrile
Ac2O acetic acid anhydride
AcO OAc acetate
AcO OAc acetate ion
AcOH HOAc, CH3COOH acetic acid
APCI atmospheric pressure chemical ionisation
a a a
a a a

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B

Term or Abbreviation Also Known As Description
BIRD bilinear rotational decoupling
Bu n-Bu butyl group
t-Bu tert-Bu tertiary-butyl group
t-BuOH tert-BuOH tertiary-butanol
t-BuOK tert-BuOK potassium tertiary-butoxide
Bu4NF TBAF tetrabutylammonium fluoride
b b b

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C

Term or Abbreviation Also Known As Description
CH3COOEt EtOAc ethyl acetate
CH3COOH HOAc, AcOH acetic acid
CH3COOMe MeOAc methyl acetate
COSY correlation spectroscopy
c c c

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D

Term or Abbreviation Also Known As Description
DCC N,N-dicyclohexylcarbodiimide
DCM CH2Cl2 dichloromethane
DEPT distortion enhancement by polarisation transfer
DFT density function theory
DIPEA diisopropylethylamine
DMAP 4-dimethylaminopyridine
DMF N,N-dimethylformamide
DMSO dimethylsulfoxide
DNMR dynamic nuclear magnetic resonance
d d d
d d d

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E

Term or Abbreviation Also Known As Description
EI electron impact
ES ESI electrospray ionisation
Et C2H5 ethyl group
EXSY exchange spectroscopy
EtOAc CH3COOEt ethyl acetate
EtOH C2H5OH ethanol
e e e
e e e

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F

Term or Abbreviation Also Known As Description
FID field induction decay
FTIR Fourier transfor infrared
f f f
f f f
f f f

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G

Term or Abbreviation Also Known As Description
GC gas chromatography
GC-MS GC/MS gas chromatography-mass spectrometry
g g g
g g g
g g g

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H

Term or Abbreviation Also Known As Description
HMBC heteronuclear multiple bond correlation
HMQC heteronuclear multiple quantum correlation
HPLC high performance liquid chromatography
HRMS high resolution mass spectrometry
HSQC heteronuclear single quantum correlation
HOAc AcOH, CH3COOH acetic acid
h h h
h h h

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I

Term or Abbreviation Also Known As Description
i-Pr isopropyl
i-PrOH isopropanol
i i i
i i i
i i i

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J

Term or Abbreviation Also Known As Description
j j j
j j j
j j j
j j j
j j j

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K

Term or Abbreviation Also Known As Description
k k k
k k k
k k k
k k k
k k k

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L

Term or Abbreviation Also Known As Description
LAH lithal, LiAlH4 lithium aluminium hydride
l l l
l l l
l l l
l l l

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M

Term or Abbreviation Also Known As Description
MALDI matrix-assisted laser desorption/ionisation
Me CH3 methyl group
MeOAc CH3COOMe methyl acetate
MeOH methanol
m m m

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N

Term or Abbreviation Also Known As Description
NMR nuclear magnetic resonance
NOESY nuclear overhauser effect spectroscopy
NaOEt NaOC2H5 sodium ethoxide
NaOMe NaOCH3 sodium methoxide
n n n

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O

Term or Abbreviation Also Known As Description
OLED organic light emitting diode
ORTEP oak-ridge thermal ellipsoid plot
o o o
o o o
o o o

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P

Term or Abbreviation Also Known As Description
ppb parts per billion
ppm parts per million
PPTS pyridinium p-toluenesulfonate
PSYCHE pure shift yielded by chirp excitation
p p p

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Q

Term or Abbreviation Also Known As Description
q q q
q q q
q q q
q q q
q q q

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R

Term or Abbreviation Also Known As Description
R alkyl/substituent group in general
r r r
r r r
r r r
r r r

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S

Term or Abbreviation Also Known As Description
SEC size exclusion chromatography
SEM scanning electron microscopy
s s s
s s s

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T

Term or Abbreviation Also Known As Description
t-Bu tert-Bu tertiary-butyl group
t-BuOH tert-BuOH tertiary-butanol
t-BuOK tert-BuOK potassium tertiary-butoxide
TBAF Bu4NF tetrabutylammonium fluoride
TBDMS TBS t-butyldimethylsilyl protecting group
TEM transmission electron microscopy
TFA CF3COOH trifluoroacetic acid
THF tetrahydrofuran
TIPS triisopropylsilyl protecting group
TLC thin layer chromatography
TMS trimethylsilyl protecting group
TMS (in NMR only) tetramethylsilane
TOCSY total correlation spectroscopy
t t t
t t t
t t t

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U

Term or Abbreviation Also Known As Description
u u u
u u u
u u u
u u u
u u u

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V

Term or Abbreviation Also Known As Description
VT NMR variable temperature nuclear magnetic resonance
v v v
v v v
v v v
v v v

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W

Term or Abbreviation Also Known As Description
w w w
w w w
w w w
w w w
w w w

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X

Term or Abbreviation Also Known As Description
x x x
x x x
x x x
x x x
x x x

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Y

Term or Abbreviation Also Known As Description
y y y
y y y
y y y
y y y
y y y

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Z

Term or Abbreviation Also Known As Description
z z z
z z z
z z z
z z z
z z z

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